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Weed killer: Discourage weeds by spreading baking soda into the cracks in your paths and driveways.

Boiling Water Weed Killer - Even easier that the vinegar weed killer is boiling water.  Pour boiling water over weeds sprouting up through walks or patios and they will wilt instantly!  Personally, I like this better than vinegar on concrete because the vinegar tends to leave a white residue behind.

Camp Wander: 10 Garden Solutions Lurking in your Pantry

Baking soda neutralizes the ph in the soil and nothing will grow there. use baking soda around all of the edges of flower beds to keep the grass and weeds from growing into beds. Just sprinkle it onto the soil so that it covers it lightly. Do this twice a year - spring and fall