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Just use a heat protectant spray
My hair will curl with an iron but then it'll be straight again after an hour or so, even with lots of hairspray. I recently discovered the elastic headband trick though, which is no-heat, takes about 5 minutes to do, and works like a charm! My hair stays wavy like this picture for the whole day WITHOUT hairspray! Google it! :)
I second the shout-out to Loepsie's Sock Bun.
If you dont want to go out and buy a curling wand, get a small barrell curling iron and just dont open the clamp and then wrap youre hair around that. it works just fine for me