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6 Homemade Recipes for Acne Free Skin. One example: 1. Honey and Apple Cider Vinegar Toner ½ tsp of honey, 1 part apple cider vinegar 8 parts of pure distilled water (Becomegorgous.com): Shake the container to mix the various elements. Use a cotton ball to apply the toner on your face. Use this toner daily.