Natural Ant Killer composed of baking soda, powdered sugar and water. They won't be able to tell the difference from the food and killer.
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You have to use it when it's not expected to rain for 36 hrs or so. Spray in the morning after the dew has evaporated. 1 qt white vinegar and c epsom salts, dish soap, mixed in water, in a sprayer bottle
A homemade natural insecticidal spray for hand-to-hand combat, a homemade ant trap to catch them all, and various "lines ants won't cross" to keep them out or contained are all found here!