Add orange peels (or any citrus peel) to a quart of white vinegar in a closed container and let it set for two weeks. Combine citrus/vinegar solution half/half with water and use for cleaning. Works on floors, tile, fixtures, etc. Smells good and is tough on scum! Best of all there are no chemicals.
Punch a hole in the top of a bottle of vinegar and sit the bottle in your toilet tank. In doing this you will save water, as the tank wont fill as much, the vinegar will clean your toilet AND tank on each flush, it leaves the bathroom smelling fresh and it doesn't harm any component of your toilet OR the environment when flushed.