Submarine (2011) -- similar to the effect in The Graduate, this film contrasts the individual in the frame alone vís-a-vís with the love interest; often created by same or similar shot, once alone, again with love interest, a third time alone.
Into the wild (2007) such a moving film. I do tend to over analyze things, but this movie really shook me to my core. Beautifully tragic. The fact that it's based off of true events makes it even more emotional.
La La Land (2016), d. Damien Chazelle, d.p. Linus Sandgren