This is George Stuart's figurine of Catherine of Aragon in a velvet dress with English hood. She was Queen of England from 1509 until 1533 as the first wife of Henry VIII and previously Princess of Wales as the wife of Prince Arthur
Henry VIII and his six wives (in order) by reconstruction artist M. Queen Catherine of Aragon, Queen Anne Boleyn, Queen Jane Seymour, Queen Anne of Cleves, Queen Catherine Howard and Queen Catherine Parr.
Good Queen Katherine Wife no. Katherine of Aragon, daughter of The Catholic Kings, Ferdinand and Isabella of Spain. Henry divorced her, bastardised their daughter Princess Mary and broke with Rome to marry his mistress Anne Boleyn.