No offense, I'm sure this is a great tutorial. But this scares the crap out of me. What is REAL in pictures anymore? "Photoshop Tutorial: Apply a Great Photoshop Colorful Effect for a Lady (entire site dedicated to photoshop tutorials)"
Highlighting and contouring in Photoshop: Fill a blank layer with grey and place it on the soft light blend mode. Then paint with either a low opacity white paintbrush to highlight or a low opacity black paintbrush to darken.