Chiana from FARSCAPE. My favorite character on the show. Interestingly the series got better once she joined halfway through S1. I think it similar to how dreary HARRY POTTER would have been without Ron.
Pa'u Zotoh Zhaan - another of the characters I'd want to spend an hour with: those themes of redemption, and choosing to be a compassionate spiritual / sexual healer after a past soaked with abuse of power and regret really resonates for me.