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paint furniture hmmmmmmmmm, I actually have these very same chairs, although one is now toast and another is breaking. I wouldn't choose white, but this might be a nice change.
If you're new to painting, I would HIGHLY recommend visiting All Things Thrifty and read her post Painting Furniture 101. This is where I started and I am sooo thankful for this post to set me in the right direction. Check out her piano transformation here! it is TO DIE FOR!