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This is a court dress worn by Alexandra on another day. Her wedding dress probably looked much like this one. The actual dress was lost during the Revolution

Coronation Dress of Alexandra Feodorovna, born Princess Charlotte of Prussia: 1825, Russian. "The silk-lined dress with a train is made of silver brocade...The item is of delicate forms, with a square cut of the bodices...The hem of the bell-shaped skirt is completed with a wadded roll and is embroidered with silver faceted threads. The long executed in the form of a thrown open dress with a little bodice and pleats on the narrowed back."