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Soak hardened paintbrushes in Murphy Oil Soap for 24 to 48 hours. It dissolves all the paint and makes it like new.
This tip has saved my brushes many, many, times. Thanks to Laura Cox of Heart of the Home Stencils who first led me to Murphy's Oil Soap! "If you petrify a brush just soak it in Murphy's for 24 to 48 hours and it dissolves all the paint and makes it like new."